1914-97-2Relevant academic research and scientific papers
Evidence for the Formation of 1,2-Dioxetane as a High-Energy Intermediate and Possible Chemiexcitation Pathways in the Chemiluminescence of Lophine Peroxides
Boaro, Andreia,Reis, Roberta Albino,Silva, Carolina Santana,Melo, Diêgo Ulysses,Pinto, Alexander Garreta Gon?alves Costa,Bartoloni, Fernando Heering
, p. 6633 - 6647 (2021/05/29)
A kinetic study of the chemiluminescent (CL) reaction mechanism of lophine-derived hydroperoxides and silylperoxides induced by a base and fluoride, respectively, provided evidence for the formation of a 1,2-dioxetane as a high-energy intermediate (HEI) o
Location effect of an OH group on the chemiluminescence efficiency of 4-hydroperoxy-2-(o-, m-, or p-hydroxyphenyl)-4,5-diphenyl-4H-isoimidazoles
Tsunenaga, Mitsuru,Iga, Hiroshi,Kimura, Masaru
, p. 1877 - 1880 (2007/10/03)
In studying the location effect of an OH group on the chemiluminescence efficiency of 4-hydroperoxy-2-(o-, m-, or p-hydroxyphenyl)-4,5-diphenyl-4H- isoimidazoles 4, we found that the efficiency of 4a with o-OH was 0.28 times that of lophine peroxide on initiation with KOH/MeOH. When the trigger base was changed to TBAF/THF, efficiency was 530-fold in dry DMF. The efficiency of 4b with m-OH or 4c with p-OH showed no such dramatic change.
