191401-73-7

Basic information

• Product Name: (4E,8E)-2-Benzenesulfonyl-2-((E)-5-hydroxy-2,6-dimethyl-hepta-1,6-dienyl)-10-(5-methoxy-2-methoxycarbonyloxy-phenyl)-4,8-dimethyl-deca-4,8-dienoic acid methyl ester
• Synonyms: (4E,8E)-2-Benzenesulfonyl-2-((E)-5-hydroxy-2,6-dimethyl-hepta-1,6-dienyl)-10-(5-methoxy-2-methoxycarbonyloxy-phenyl)-4,8-dimethyl-deca-4,8-dienoic acid methyl ester
• CAS NO: 191401-73-7
• Molecular Weight: 668.849
• Mol File: 191401-73-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4E,8E)-2-Benzenesulfonyl-2-((E)-5-hydroxy-2,6-dimethyl-hepta-1,6-dienyl)-10-(5-methoxy-2-methoxycarbonyloxy-phenyl)-4,8-dimethyl-deca-4,8-dienoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (4E,8E)-2-Benzenesulfonyl-2-((E)-5-hydroxy-2,6-dimethyl-hepta-1,6-dienyl)-10-(5-methoxy-2-methoxycarbonyloxy-phenyl)-4,8-dimethyl-deca-4,8-dienoic acid methyl ester(191401-73-7)
• EPA Substance Registry System: (4E,8E)-2-Benzenesulfonyl-2-((E)-5-hydroxy-2,6-dimethyl-hepta-1,6-dienyl)-10-(5-methoxy-2-methoxycarbonyloxy-phenyl)-4,8-dimethyl-deca-4,8-dienoic acid methyl ester(191401-73-7)

Safety Data

• Hazardous Substances Data: 191401-73-7(Hazardous Substances Data)

Upstream product

• 191401-66-8 2-((E)-6-Hydroxy-3,7-dimethyl-octa-2,7-dienyl)-4-methoxy-phenol 
• 191401-69-1 (E)-8-Benzenesulfonyl-2,6-dimethyl-octa-1,6-dien-3-ol 
• 191401-65-7 2-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyl]-4-methoxy-phenol 
• 79233-10-6 (E)-2-(3,7-dimethylocta-2,6-dien-1-yl)-4-methoxyphenol 
• 74832-85-2 6,7-oxido-3,7-dimethyl-1-(benzenesulfonyl)-(2E)-octene 
• 873-55-2 sodium benzenesulfonate 
• 56691-80-6 geranyl phenyl sulfone 
• 106-24-1 Geraniol 
• 6138-90-5 trans-geranyl bromide 
• 191401-70-4 (E)-2-Benzenesulfonyl-7-hydroxy-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-67-9 Carbonic acid 4-methoxy-2-((E)-6-methoxycarbonyloxy-3,7-dimethyl-octa-2,7-dienyl)-phenyl ester methyl ester 

Downstream Products

• 191401-74-8 (4E,8E)-2-Benzenesulfonyl-2-((E)-5-methoxycarbonyloxy-2,6-dimethyl-hepta-1,6-dienyl)-10-(5-methoxy-2-methoxycarbonyloxy-phenyl)-4,8-dimethyl-deca-4,8-dienoic acid methyl ester 
• 35890-86-9 2-<(2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27-heptamethyloctacosa-2,6,10,14,18,22,26-heptaenyl>-1,4-benzoquinone 
• 35890-89-2 2-<(2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27-heptamethyloctacosa-2,6,10,14,18,22,26-heptaenyl>benzene-1,4-diol 
• 191401-83-9 2-((2E,6E,10E,14E,18E,22E,26E)-3,7,11,15,19,23,27-heptamethyloctacosa-2,6,10,14,18,22,26-heptaenyl)-4-methoxyphenol 
• 191401-80-6 2-((2E,6E,10E,14E,18E,22E)-9,17-Bis-benzenesulfonyl-3,7,11,15,19,23,27-heptamethyl-octacosa-2,6,10,14,18,22,26-heptaenyl)-4-methoxy-phenol 
• 191401-77-1 (3E,7E)-2,10-Bis-benzenesulfonyl-2-[(2E,6E)-8-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2,6-dimethyl-octa-2,6-dienyl]-4,8-dimethyl-10-((1E,5E)-2,6,10-trimethyl-undeca-1,5,9-trienyl)-undeca-3,7-dienedioic acid dimethyl ester 

Relevant articles and documents

Total synthesis of polyprenylhydroquinols and benzoquinones

The total synthesis of polyprenylhydroquinols and benzoquinones is described.First, two appropriate aromatic allyl carbonates (moieties with one and two prenyls) and two activated bifunctional terpenyl derivatives (moieties with two and three prenyls) were synthesized.These molecules were then reacted together using a highly regio- and stereoselective coupling with Pd(PPh3)4 as a catalyst.The synthesis was achieved by functional group elimination and formation of quinonic and hydroquinonic moieties. - Keywords: polyprenylbenzoquinol; polyprenylhydroquinone; allylcarbonate; ?-allyl palladium complex