191598-01-3Relevant academic research and scientific papers
( Z)-1-Methoxy-4-( diphenylphosphino) but-1-ene-3-yne: A versatile synthon for unsymmetrically substituted ( diphenylphosphino) diacetylene derivatives
Corriu, Robert J.P.,Guerin, Christian,Henner, Bernard J.L.,Jolivet, Agnes
, p. 39 - 48 (2007/10/03)
An efficient synthesis of Ph2P-C≡C-C≡C-Li, 1, was found, starting from commercially available (Z)-1-methoxybut-1-ene-3-yne and its diphenylphosphino derivative 2. The lithio compound 1 was condensed with electrophiles to give Ph2P-C≡
