191614-91-2Relevant academic research and scientific papers
Reactions of l-chloro-l-phosphirenes with nucleophiles
Heydt, Heinrich,Ehle, Michael,Haber, Steffen,Hoffmann, Juergen,Wagner, Oliver,Goeller, Andreas,Clark, Timothy,Regitz, Manfred
, p. 711 - 723 (2007/10/03)
The halogen atoms in the 1-chloro-lH-phosphirenes, 5a-c, are easily substituted on reaction with organolithium and Grignard reagents, 14a-p, with formation of the corresponding O-, N-, C-, Si-, and Ge-substituted IH-phosphirenes, 15a-t. Cl/H exchange reactions also occur on reaction with lithium metal hydrides (5a → 17). Furthermore, substitution reactions are also realized with the alkali metal borates, 18a-g (→19a-g); the same is true for reactions with trimethylsilyl cyanide and azide (→22a-d). Some of the substitution products have been characterized in the form of their metal complexes, 16, 23, 24, and 25. VCH Verlagsgesellschaft mbH,.
