191654-69-0

Basic information

• Product Name: [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
• Synonyms: [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride;[PdCl2{(R)-4-tolylbinap}]
• CAS NO: 191654-69-0
• Molecular Formula: C₄₈H₄₀Cl₂P₂Pd
• Molecular Weight: 856.104722
• Mol File: 191654-69-0.mol
• Article Data: 1

Chemical Properties

• Melting Point: >300°C
• Appearance: /
• CAS DataBase Reference: [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride(CAS DataBase Reference)
• NIST Chemistry Reference: [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride(191654-69-0)
• EPA Substance Registry System: [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride(191654-69-0)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 191654-69-0(Hazardous Substances Data)

Usage

Uses

Catalyst for:Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetalStereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactantsStereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzincReactant for:Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes

Upstream product

• 13965-03-2 bis-triphenylphosphine-palladium(II) chloride 
• 153305-67-0 (+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl 
• 21264-30-2 dichloro bis(acetonitrile) palladium(II) 

Relevant articles and documents

New developments in the Pd-catalysed cyclisation-coupling reaction of alkene-containing carbonucleophiles with organic halides (and triflates). The first examples of asymmetric catalysis

The results of our preliminary investigations directed toward asymmetric catalysis of the cyclocarbopalladation of alkenes bearing a proximate nucleophile with organic halides (or triflates) are disclosed. A series of bidentate phosphine ligands were eval