191680-68-9Relevant academic research and scientific papers
A New Lithium 5-Methyl-1,3-dithia-5-azacyclohex-2-ylborate-5-Borane and Two Dimeric 5-Methyl-1,3-dithia-5-azacyclohex-2-yllithium Compounds - Stereochemistry and Reactivity
Guadarrama-Perez, Carlos,Cadenas-Pliego, Gregorio,Martinez-Aguilera, Luz Maria R.,Flores-Parra, Angelina
, p. 813 - 817 (1997)
Syntheses of the dimers of axial 5-methyl-2-dithiazinyllithium (4) and equatorial 5-methyl-2-dithiazinyllithium-5-borane (5), and lithium 5-methyl-2-dithiazinanylborate-5-borane (6) are reported. Compounds 4, 5, and 6 are configurationally and conformationally stable. The 1H-, 13C-, 11B-, and 7Li-NMR study of the reactions of 4 and 5 with BH3-S(CH3)2, BH3-THF, and CH3I is presented. VCH Verlagsgesellschaft mbH,.
