191804-69-0

Basic information

• Product Name: Cu(O₂NC₆H₄NHCSNHCOOCH₂CH₃)2Cl
• CAS NO: 191804-69-0
• Molecular Weight: 637.561
• Mol File: 191804-69-0.mol

Chemical Properties

• CAS DataBase Reference: Cu(O₂NC₆H₄NHCSNHCOOCH₂CH₃)2Cl(CAS DataBase Reference)
• NIST Chemistry Reference: Cu(O₂NC₆H₄NHCSNHCOOCH₂CH₃)2Cl(191804-69-0)
• EPA Substance Registry System: Cu(O₂NC₆H₄NHCSNHCOOCH₂CH₃)2Cl(191804-69-0)

Safety Data

• Hazardous Substances Data: 191804-69-0(Hazardous Substances Data)

Upstream product

• 35196-21-5 N-(o-nitrophenyl)-N'-(ethoxycarbonyl)-thiourea 

Relevant articles and documents

Syntheses and crystal structures of copper(I) complexes with alkyl-thioallophanate derivatives

The reaction of CuCl2 · 2H2O with N-(p-nitrophenyl)-N′-butoxycarbonyl)-thiourea (H2nbt) and N-(o-nitrophenyl)-N′-(ethoxycarbonyl)-thiourea (H2net) gave two copper(I) complexes, [Cu(H2nbt)2Cl]2, 1, and Cu(H2net)2Cl, 2, respectively. In complex 1, the ligand H2nbt is S,S-bonded to two Cu atoms, and the two ligand molecules exchange long Cu - S interactions (Cu -S = 2.700 A?) forming a dimer, in which the Cu atom has a distorted tetrahedral coordination [Cl - Cu - S(1) = 119.9(1), Cl - Cu - S(2) = 122.9(1) and S(1) - Cu - S(2) = 108.4(1)°] and is 0.387(2) A? from th basal S, S, Cl with unequal Cu - S [2.253(3), 2.244(3) A?] and Cu - Cl [2.247(3) A?] bonds. In complex 2, the copper (I) atom is in a trigonal planar geometry [Cl - Cu - S(1) = 120.53(5), Cl - Cu - S(2) = 118.43(5) and S(1) - Cu -S(2) = 119.16(5)°] with two unequal Cu - S [2.228(1), 2.232(1) A?] and Cu - Cl [2.251(1) A?] bonds.