19185-59-2

Upstream product

• 108-98-5 thiophenol 
• 762-72-1 allyl-trimethyl-silane 
• 10545-34-3 3-(trimethylsilyl)propyl bromide 
• 3111-52-2 potassium thiophenolate 

Downstream Products

• 89373-24-0 Trimethyl-(3-phenylsulfanyl-heptyl)-silane 
• 89373-25-1 Trimethyl-(5-methyl-3-phenylsulfanyl-hexyl)-silane 
• 89373-21-7 (E)-trimethyl(4-phenylbut-3-enyl)silane 
• 89373-22-8 Trimethyl-((E)-4-p-tolyl-but-3-enyl)-silane 
• 89373-10-4 (3-Benzenesulfinyl-5-methyl-hex-5-enyl)-trimethyl-silane 
• 89373-09-1 (3-Benzenesulfinyl-5-methyl-hexyl)-trimethyl-silane 
• 89373-08-0 (3-Benzenesulfinyl-heptyl)-trimethyl-silane 
• 89373-11-5 (3-Benzenesulfinyl-4-phenyl-butyl)-trimethyl-silane 
• 89373-12-6 (3-Benzenesulfinyl-4-p-tolyl-butyl)-trimethyl-silane 
• 89373-07-9 (3-Benzenesulfinyl-undecyl)-trimethyl-silane 
• 89384-32-7 C₂₃H₃₅NO₂S₂Si 
• 89373-27-3 C₂₃H₃₅NO₂S₂Si 
• 89373-26-2 C₂₇H₄₃NO₂S₂Si 
• 89373-23-9 Trimethyl-(3-phenylsulfanyl-undecyl)-silane 

Relevant academic research and scientific papers

Scandium(III) Triflate-Catalyzed anti-Markovnikov Hydrothiolation of Functionalized Olefins

Scandium(III) triflate promoted highly selective addition of thiols to functionalized olefins under mild conditions. The addition follows anti-Markovnikov regioselectivities, which are unusual for Lewis acids-catalyzed hydrothiolation. This reaction marks broad functional groups tolerance, which opens a beneficial synthetic route to functionalized and biologically active thio-compounds. This method is broadly applicable and offers a simple work-up in the green manner.

REGIOSELECTIVE SYNTHESIS OF 3-ALKENYLSILANES AND 3-ALKENYLSTANNANES BY SILICON- AND TIN-DIRECTED ELIMINATION FROM γ-SILYL AND γ-STANNYL SUBSTITUTED SULFOXIDES AND SULFILIMINES

3-Alkenylsilanes and 3-alkenylstannanes are conveniently prepared by the silicon- and tin-directed regioselective elimination of sulfenic acid and sulfenamide from γ-silyl and γ-stannyl substituted sulfoxides and sulfilimines.