1919-64-8Relevant articles and documents
Efficient access to: cis -decalinol frameworks: copper(i)-catalyzed borylative cyclization of allene cyclohexanediones
Zhao, Yi-Shuang,Tang, Xiao-Qi,Tao, Jing-Chao,Tian, Ping,Lin, Guo-Qiang
supporting information, p. 4400 - 4404 (2016/06/06)
Cu-catalyzed borylative cyclization of allene cyclohexanediones has been described through a tandem β-borylation and intramolecular allylic addition process, affording borylated cis-decalinols with excellent yields and diastereoselectivities. A good enantioselectivity is also achieved in the asymmetric version. The hemiboronate group in the cyclization products could be subjected to several useful transformations.