191991-89-6

Basic information

• Product Name: Co(ONC(CH₃)C(CH₃)NOH)2(C₅H₅N)(CH₂SC₄H₂SC₆H₅)
• CAS NO: 191991-89-6
• Molecular Weight: 573.643
• Mol File: 191991-89-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Co(ONC(CH₃)C(CH₃)NOH)2(C₅H₅N)(CH₂SC₄H₂SC₆H₅)(CAS DataBase Reference)
• NIST Chemistry Reference: Co(ONC(CH₃)C(CH₃)NOH)2(C₅H₅N)(CH₂SC₄H₂SC₆H₅)(191991-89-6)
• EPA Substance Registry System: Co(ONC(CH₃)C(CH₃)NOH)2(C₅H₅N)(CH₂SC₄H₂SC₆H₅)(191991-89-6)

Safety Data

• Hazardous Substances Data: 191991-89-6(Hazardous Substances Data)

Upstream product

• 92785-15-4 Co(ONC(CH₃)C(CH₃)NOH)2(pyridine)(3-thienylmethyl) 
• 931-59-9 benzenesulfenyl chloride 

Relevant articles and documents

Co-C bond cleavage in the reactions of alkyl, benzyl and heteroaromaticmethyl cobaloximes with arene sulfenyl chloride: Homolytic and heterolytic pathways

The reactions of arene sulfenyl chlorides, ArSCl, (Ar=Ph, C6Cl5, 2,4 (NO2)2C6H3) with organocobaloximes, RCo(dmgH)2Py, (R=alkyl, benzyl and heteroaromaticmethyl) were carried out under thermal and photochemical conditions. A variety of organic and organometallic products are formed depending upon the substrate cobaloxime. For 3-methoxybenzyl and heteroaromaticmethyl cobaloximes the results suggest that they represent a unique class of cobaloximes whereby both the aromatic ring as well as the Co-C bond are highly activated towards attack by the arene sulfenyl chloride. Both homolytic as well as heterolytic pathways are operative.