191991-93-2Relevant academic research and scientific papers
Synthesis of organocobaloximes: Modification of the organic group in organocobaloximes
Gupta,Dixit, Vandana
, p. 261 - 264 (2007/10/03)
5-Substituted heteroaromaticmethyl cobaloximes are synthesized by a very simple reaction of arenesulfenyl chloride, ArSCI (Ar = Ph, C6Cl5 and 2,4-(NO2)2C6H3) with heteroaromaticmethyl cobaloximes, RCoIII(dmgH)2Py [R = 2-and 3-thienylmethyl, furfuryl] in the dark at 0°C. As organocobaloximes are susceptible to Co-C bond cleavage by the electrophiles and free radicals, the ring substitution is quite remarkable.
