19200-26-1

Basic information

• Product Name: 1-S-(dimethylcarbamothioyl)-1-thio-beta-D-glucopyranose
• CAS NO: 19200-26-1
• Molecular Formula: C₉H₁₇NO₅S₂
• Molecular Weight: 283.365
• Mol File: 19200-26-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 489.7°C at 760 mmHg
• Flash Point: 250°C
• Density: 1.53g/cm³
• Vapor Pressure: 1.2E-11mmHg at 25°C
• Refractive Index: 1.665
• CAS DataBase Reference: 1-S-(dimethylcarbamothioyl)-1-thio-beta-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-S-(dimethylcarbamothioyl)-1-thio-beta-D-glucopyranose(19200-26-1)
• EPA Substance Registry System: 1-S-(dimethylcarbamothioyl)-1-thio-beta-D-glucopyranose(19200-26-1)

Safety Data

• Hazardous Substances Data: 19200-26-1(Hazardous Substances Data)

Upstream product

• 2280-44-6 D-Glucose 
• 128-04-1 sodium dimethyldithiocarbamate 

Downstream Products

• 154-58-5 1,5-anhydro-D-glucitol 
• 106756-74-5 (2R,3R,4R,5S,6R)-2-allyl-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol 
• 96689-92-8 α-1-deoxy-1-(C-1'-phenethyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose 
• 19200-24-9 2,3,4,6-tetra-O-acetyl N,N-dimethyl S-β-glucopyranosyl dithiocarbamate 

Relevant articles and documents

Protection-free synthesis of glycosyl dithiocarbamates in aqueous media by using 2-chloroimidazolinium reagent

Glycosyl dithiocarbamates (GDTCs) have been synthesized directly from the corresponding unprotected sugars and dithiocarbamate salts in good yields by using 2-chloro-1,3-dimethylimidazolinium chloride (DMC) as condensing agent in aqueous media. The three-component one-pot synthesis of GDTCs starting from unprotected sugars, carbon disulfide, and secondary amines has also been successfully demonstrated. This is the first report on the direct synthesis of GDTCs from unprotected sugars without using any protecting groups.

First protection-free protocol for synthesis of 1-deoxy sugars through glycosyl dithiocarbamate intermediates

A practical two-step synthetic process for 1-deoxy sugars has been established. The process consists of the direct introduction of a dimethyldithiocarbamate group into the anomeric center of unprotected sugars and subsequent hydrogenation in the AIBN-H3PO2-NaHCO3 system. No protecting groups are needed to synthesize 1-deoxy monosaccharides and 1-deoxy disaccharides.