192051-21-1

Basic information

• Product Name: ethanethioic acid S-2-cyclohexen-1-yl ester
• Synonyms: ethanethioic acid S-2-cyclohexen-1-yl ester
• CAS NO: 192051-21-1
• Molecular Weight: 156.249
• Mol File: 192051-21-1.mol

Chemical Properties

• CAS DataBase Reference: ethanethioic acid S-2-cyclohexen-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: ethanethioic acid S-2-cyclohexen-1-yl ester(192051-21-1)
• EPA Substance Registry System: ethanethioic acid S-2-cyclohexen-1-yl ester(192051-21-1)

Safety Data

• Hazardous Substances Data: 192051-21-1(Hazardous Substances Data)

Upstream product

• 58329-99-0 cyclohex-2-enyl methyl carbonate 
• 10387-40-3 potassium thioacetate 
• 1521-51-3 rac-3-bromocyclohexene 

Downstream Products

• 96080-58-9 bis(2-cyclohexen-1-yl)disulfide 

Relevant articles and documents

Palladium-catalyzed synthesis of allylic thioacetates. A convenient access to allylic thiols

Palladium(0)-catalyzed alkylation of various allylic acetates and carbonates by potassium thioacetate allowed an easy access to allylic thioacetates in rather good yields. The reaction was regioselective with substitution at the less hindered side of the intermediate π-allyl system, and diastereoselective with net retention of configuration.

Liquid sulfur as a reagent: Synthesis of polysulfanes with 20 or more sulfur atoms with characterization by UPLC-(Ag+)-coordination ion spray-MS

Diallyl disulfide reacts within minutes with liquid sulfur at 120°C giving a family of diallyl polysulfanes, All2S n (n=3-22), characterized by ultra-performance liquid chromatography-(Ag+)-coordination ion spray-mass spectrometry (UPLC-(Ag+)CIS-MS). Similarly, garlic oil (GO), bis-(2-methyl-2-propenyl), bis-(2-chloro-2-propenyl), bis-(3-methyl-2- butenyl), and bis-(2-cyclohexen-1-yl) disulfides all give families of polysulfanes with up to 22 sequential sulfur atoms. New members of families of silver chelators with up to 10 sulfur atoms were found in GO using UPLC-(Ag +)CIS-MS. 2013 Copyright Taylor and Francis Group, LLC.