192139-90-5

Basic information

• Product Name: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
• Synonyms: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II);[N-[(1S,2S)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-methylethyl)benzene]-ruthenium;RuCl(p-cymene)[(S,S)-Ts-DPEN];Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II);Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%;Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene);[N-[(1S,2S)-2-(Amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-n)-1-methyl-4-(1-methylethyl)benzene]ruthenium;Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
• CAS NO: 192139-90-5
• Molecular Formula: C₃₁H₃₄ClN₂O₂RuS
• Molecular Weight: 631.17
• Product Categories: organometallic complex;Ru
• Mol File: 192139-90-5.mol
• Article Data: 3

Chemical Properties

• Melting Point: >175 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: yellow to dark brown/solid
• Density: g/cm³
• Storage Temp.: 2-8°C
• Sensitive: air sensitive
• CAS DataBase Reference: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)(192139-90-5)
• EPA Substance Registry System: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)(192139-90-5)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• Safety Statements: 24/25
• WGK Germany: 3
• Hazardous Substances Data: 192139-90-5(Hazardous Substances Data)

Usage

Reaction

This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.

Chemical Properties

Solid

Uses

Different sources of media describe the Uses of 192139-90-5 differently. You can refer to the following data:
1. Catalyst involved in: ? Asymmetric transfer hydrogenation of imines and ketones ? Intramolecular asymmetric reductive amination ? Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of arenerut
2. Catalyst involved in:Asymmetric transfer hydrogenation of imines and ketonesIntramolecular asymmetric reductive aminationTandem hydroformylation / hydrogenation of terminal olefinsReactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

General Description

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

InChI:InChI=1/C21H21N2O2S.C10H20.CH3.ClH.Ru/c1-16-12-14-19(15-13-16)25(24)26-23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;;/h2-15,20-22,24H,1H3;8-10H,4-7H2,1-3H3;1H3;1H;/q-2;;;;+3/p-1/t20-,21-;9-,10+;;;/m0..../s1/rC22H24ClN2O2RuS.C10H20/c1-17-13-15-20(16-14-17)27(26)29-25-22(19-11-7-4-8-12-19)21(24-28(25,2)23)18-9-5-3-6-10-18;1-8(2)10-6-4-9(3)5-7-10/h3-16,21-22,24,26H,1-2H3;8-10H,4-7H2,1-3H3/t21-,22-;9-,10+/m0./s1

Upstream product

• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 144222-34-4 (R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine 
• 167316-27-0 N-[(1S,2S)-2-amino-1,2-diphenylethyl]-4-methylbenzenesulfonamide 

Downstream Products

• 188444-43-1 [RuH(η⁶-p-cymene)(N-tosyl-1,2-diphenylethylenediamine)] 

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