192184-77-3Relevant academic research and scientific papers
9-Adamantylidene-10-alkyl-9,10-dihydroacridine oxide as a novel and potential chemiluminescent precursor: Proximity effect of the nitrogen atom
Imanishi, Takeshi,Ueda, Yohko,Minagawa, Masatoshi,Hoshino, Nobuhiro,Miyashita, Kazuyuki
, p. 3967 - 3970 (1997)
An oxirane derivative having acridane and adamantane moieties was prepared and proved to show potential chemiluminescent property on treatment with alkaline hydroperoxide and subsequently with hydrochloric acid, in which the electron-donating property of the nitrogen was experimentally shown to play an important role for the chemiluminescences.
Oxiranes having an acridane structure as a novel chemiluminescent precursor: Synthesis and chemiluminescent studies
Miyashita, Kazuyuki,Minagawa, Masatoshi,Ueda, Yohko,Tada, Yukie,Hoshino, Nobuhiro,Imanishi, Takeshi
, p. 3361 - 3367 (2001)
Oxirane derivatives having acridane and adamantane structures were designed as a novel chemiluminescent precursor and were found to have a characteristic chemiluminescent ability which is introduced by a two-step trigger reaction involving treatment with alkaline H2O2 and subsequent acidic treatment. Structural study of the oxirane derivatives showed that the CIEEL mechanism is involved in this chemiluminescent reaction and it was also found that the chemiluminescent profile is affected by the kind of acid employed in the trigger reaction.
Thermal and chemiluminescent property of dioxetanes having an N-arylacridane structure
Imanishi, Takeshi,Ueda, Yohko,Tainaka, Ryoh,Kuni, Naoto,Minagawa, Masatoshi,Hoshino, Nobuhiro,Miyashita, Kazuyuki
, p. 829 - 838 (2007/10/03)
Novel dioxetanes having an N-arylacridane structure were synthesized. Studies on thermal stability and chemiluminescent property of these . compounds showed that the aryl group cannot stabilize the dioxetane structure so much but can trigger the chemiluminescence by formation of the phenoxy anion.
