192190-47-9Relevant academic research and scientific papers
Gold(I) complexes of n-thiocarbamoyl benzamidines: Synthesis and structures
Richter,Schroeder,Kampf,Hartung,Beyer
, p. 1021 - 1026 (2008/10/09)
By reaction of tetrachlorogold(III) acid with N-thiocarbamoyl benzamidines HL complexes of composition AuI(HL)Cl have been obtained. The molecular structures of three complexes have been determined by single crystal X-ray diffraction methods. All complexes show linear coordination in which the ligand HL coordinates by the S atom and the second coordination site of gold(I) is occupied by a chloro ligand. The bond lengths in the coordinated ligands HL do not change appreciably in comparison with the free ligands. In all investigated structures intermolecular hydrogen bonds of the type N-H ... Cl are formed.
