192225-62-0Relevant academic research and scientific papers
Versatile behavior of a new class of bicyclic compounds: Zirconacyclopentadiene phosphiranes
Mahieu, Armelle,Miquel, Yannick,Igau, Alain,Donnadieu, Bruno,Majoral, Jean-Pierre
, p. 3086 - 3088 (2008/10/08)
Diacetylenic phosphanes are cleanly transformed when reacted with zirconocene into zirconacyclopentadiene phosphiranes. These new cyclic systems are the source of a variety of unsaturated phosphorus compounds like phospharadialene or alkenyl alkynyl phosphanes.
Phosphorus and zirconium: A fruitful rendez-vous
Majoral, Jean-Pierre,Igau, Alain,Zablocka, Maria,Mahieu, Armelle,Cenac, Nathalie,Pietrusiewicz, Michal K.
, p. 185 - 188 (2007/10/03)
Zirconium reagents such as [Cp2ZrHCl]n, Cp2ZrMe2, [Cp2Zr] ... were found to be useful tools for the regio and diastereospecific synthesis of diphosphines including optically active diphosphines as well as for the generation of masked iminophosphide anions, metalated phosphorus containing macrocycles, phosphirane zirconacyclopentadienes or zirconacyclopropenes.
