192228-62-9Relevant academic research and scientific papers
Alternative mechanisms of the alkyne to vinylidene isomerization promoted by half-sandwich ruthenium complexes. X-ray crystal structure of [Cp*Ru = C = CHCOOMe(dippe)][BPh4] and [Cp*RuH(C ≡ CCOOMe(dippe)][BPh4] (dippe = 1,2-bis(diiso
De Los Ríos, Isaac,Jiménez Tenorio, Manuel,Puerta, M. Carmen,Valerga, Pedro
, p. 6529 - 6538 (1997)
The complex [Cp*RuCl(dippe)] reacts with 1-alkynes in MeOH in the presence of NaBPh4, yielding the metastable hydrido-alkynyl derivatives [Cp*Ru(H)(C ≡ CR)(dippe)][BPh4] (R = COOMe, Ph or SiMe3), intermediates in the forma
