192506-64-2Relevant academic research and scientific papers
New glycosylation reaction based on alkyne-Co2(CO)6 complex
Mukai, Chisato,Itoh, Takahiro,Hanaoka, Miyoji
, p. 4595 - 4598 (2007/10/03)
O-Protected glycopyranoside possessing 4-(O-protected-glucosyl)-6-phenyl-5-hexynoate residue at anomeric position was converted into the corresponding cobalt complex, which on exposure to trimethylsilyl trifluoromethanesulfonate afforded glucosylglucoside derivative in a good yield via internal delivery of glycosyl acceptor, Similar O-protected galactopyranoside and mannopyranoside derivatives provided the corresponding galactosylglucoside and mannosylglucoside derivative, respectively.
