192565-67-6

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 260403-59-6 1-deoxy-2-O-(3,3-dimethyl-2-oxobutyl)-3,4-O-isopropylidene-1-phenylsulfonyl-6-O-triisopropyl-α-D-galactopyranose 
• 5469-26-1 1-Bromopinacolon 
• 192565-74-5 (3aS,4R,6R,7R,7aR)-2,2-Dimethyl-6-phenylsulfanyl-4-triisopropylsilanyloxymethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol 
• 260403-58-5 1-deoxy-2-O-(3,3-dimethyl-2-oxobutyl)-3,4-O-isopropylidene-1-phenylsulfenyl-6-O-triisopropylsilyl-α-D-galactopyranose 

Relevant academic research and scientific papers

Template-directed intramolecular c-glycosidation. Cation- mediated synthesis of ketooxetanes from thioglycosides

Bicyclic ketooxetanes may be assembled using cation-mediated cyclisation reactions of thioglycosides possessing silyl enol ether-containing side-chains.

Template-directed intramolecular C-glycosidation. Stereoselective synthesis of bicyclic ketooxetanes from anomeric sulfones

The Lewis acid-mediated cyclisations of sugar-derived anomeric sulfone-enol ethers 5 and 6 to give respectively the bicyclic ketooxetanes 11/12 and 16/17 are reported.