192565-69-8

Upstream product

• 5469-26-1 1-Bromopinacolon 
• 260403-42-7 1-deoxy-3,5-di-O-benzyl-1-phenylsulfenyl-D-xylofuranose 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 
• 100-44-7 benzyl chloride 
• 20881-04-3 1,2:3,5-di-O-isopropylidene-D-xylofuranose 
• 41341-99-5 3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 16054-77-6 3,5-di-O-benzyl-D-xylofuranose 

Downstream Products

• 192565-68-7 {1-[1-((3R,4S,5R)-4-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-yloxy)-meth-(Z)-ylidene]-2,2-dimethyl-propoxy}-tert-butyl-dimethyl-silane 
• 260403-56-3 1-deoxy-3,5-di-O-benzyl-2-O-(3,3-dimethyl-2-oxobutyl)-1-phenylsulfonyl-D-xylofuranose 

Relevant academic research and scientific papers

Template-directed intramolecular c-glycosidation. Cation- mediated synthesis of ketooxetanes from thioglycosides

Bicyclic ketooxetanes may be assembled using cation-mediated cyclisation reactions of thioglycosides possessing silyl enol ether-containing side-chains.

Template-directed intramolecular C-glycosidation. Stereoselective synthesis of bicyclic ketooxetanes from anomeric sulfones

The Lewis acid-mediated cyclisations of sugar-derived anomeric sulfone-enol ethers 5 and 6 to give respectively the bicyclic ketooxetanes 11/12 and 16/17 are reported.