192820-50-1Relevant academic research and scientific papers
Synthesis, characterization and structure of ferrocenylketimine complexes of platinum(II)
Wu, Yang Jie,Ding, Li,Wang, Hong Xing,Liu, Yuan Hong,Yuan, Han Zhen,Mao, Xi An
, p. 49 - 58 (2007/10/03)
The reactions of ferrocenylketimines [(η5-C5H4CMe=NAr)Fe(η5-C5H5)] (Ar = a variety of substituted phenyls) with cis-Pt(DMSO)2Cl2 in refluxing toluene have led to the formation of both the five-membered cycloplatinated derivatives [σ-Pt{(η5-C5H3CMe=NAr)Fe(η5-C5H5)}(DMSO)Cl] in the presence of sodium acetate and the coordinated compounds [trans-PtCl2(DMSO){(η5-C5H4CMe=NAr)Fe(η5-C5H5)}] in the absence of sodium acetate. The compounds have been characterized by elemental analysis, IR, 1H NMR and two-dimensional NOESY spectra. The X-ray crystal structures of [σ-Pt{(η5-C5H3CMe=NPh)Fe(η5-C5H5)}(DMSO)Cl] and [trans-PtCl2(DMSO){(η5-C5H4CMe=NPh)Fe(η5-C5H5)}] have been determined.
