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[(η(5)-C5EtMe4)2ZrCl(PH(cyclohexyl))] [(η5-C5EtMe4)2ZrCl(PH(cyclohexyl))] (also referred to as **Cp°2ZrCl(PHCy)** or **1**) is a zirconocene complex featuring a cyclohexylphosphido (PHCy) ligand and a chloride ligand coordinated to the zirconium center, with two η5-coordinated C5EtMe4 (Cp°) rings. [(η(5)-C5EtMe4)2ZrCl(PH(cyclohexyl))] serves as a precursor for insertion reactions, enabling the formation of novel P-functionalized ligands through reactions with substrates such as CS2 or isocyanates (RNCX). Its reactivity highlights its utility in organometallic synthesis for constructing phosphorus-containing frameworks. **Other names:** - Cp°2ZrCl(PHCy) - [Cp°2ZrCl(PHCy)] - (Pentamethylcyclopentadienyl)(ethyltetramethylcyclopentadienyl)zirconium(IV) chloride cyclohexylphosphido

192864-30-5

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192864-30-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 192864-30-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,9,2,8,6 and 4 respectively; the second part has 2 digits, 3 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 192864-30:
(8*1)+(7*9)+(6*2)+(5*8)+(4*6)+(3*4)+(2*3)+(1*0)=165
165 % 10 = 5
So 192864-30-5 is a valid CAS Registry Number.

192864-30-5Upstream product

192864-30-5Relevant academic research and scientific papers

Formation of novel P-functionalized ligands by insertion reactions into the Zr - P bond of Cpo2ZrCl(PHCy) (Cpo = η5-C5EtMe4, Cy = cyclohexyl)

Segerer, Ulrike,Hey-Hawkins, Evamarie

, p. 2537 - 2545 (1997)

Cpo2ZrCl2 (Cpo = η5-C5EtMe4) reacts with LiPHCy (Cy = cyclohexyl) with the formation of CPo2ZrCl(PHCy) (1). Compound 1 undergoes insertion of CS2

Formation of novel p-functionalized ligands by insertion reactions of RNCX (R = Ph, X = O, S; R = Pri, X = O) into the Zr-P bond of [Cp°2ZrCl(PHCy)] (Cp° = η5-C5EtMe4, Cy = Cyclohexyl) and [Cp′2<

Segerer,Sieler,Hey-Hawkins

, p. 2445 - 2449 (2000)

[Cp°2ZrCl(PHCy)] (1; Cp° = η5-C5EtMe4, Cy = cyclohexyl) and [Cp′2ZrCl{PH(TRIP)}] (2; Cp′ = η5-C5MeH4, TRIP = 2,4,6-Pri3C6H2

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