192931-85-4

Upstream product

• 192931-86-5 5-deoxy-1,2-O-isopropylidene-3-O-methyl-α-D-ribo-hexofuranose 
• 192931-96-7 (3aR,5R,6R,6aR)-6-Methoxy-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 192931-88-7 (E)-(4S,5R)-5,7-Dihydroxy-4-methoxy-2-methyl-hept-2-enoic acid methyl ester 
• 863036-95-7 (E)-(4S,5R)-5-Benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-4-methoxy-2-methyl-hept-2-enoic acid methyl ester 
• 192931-97-8 (E)-(4S,5R)-7-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-4-methoxy-2-methyl-hept-2-enoic acid methyl ester 
• 32166-82-8 Methanesulfonic acid (R)-2-methanesulfonyloxy-1-((3aR,5S,6R,6aR)-6-methoxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl ester 
• 18968-50-8 1-[6-methoxy-2,2-dimethyl-(3aR,5R,6R,6aR)-perhydrofuro-[2,3-d][1,3]dioxol-5-yl]-(1R)-ethane-1,2-diol 
• 192931-98-9 (E)-(4S,5R)-5-Benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-4-methoxy-2-methyl-hept-2-en-1-ol 

Downstream Products

• 192931-90-1 Benzyloxy-acetic acid (E)-(1S,4S,5R)-1-allyl-5-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-4-methoxy-2-methyl-hept-2-enyl ester 
• 192931-91-2 (E)-(2S,3S)-2-Benzyloxy-3-[(1S,2R)-2-benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-1-methoxy-butyl]-4-methyl-octa-4,7-dienoic acid methyl ester 
• 192931-84-3 (E)-(2S,3S)-2-Benzyloxy-3-[(1S,2R)-2-benzyloxy-1-methoxy-4-(toluene-4-sulfonyloxy)-butyl]-4-methyl-octa-4,7-dienoic acid methyl ester 
• 192932-01-7 (E)-(2S,3S)-2-Benzyloxy-3-((1S,2R)-2-benzyloxy-4-hydroxy-1-methoxy-butyl)-4-methyl-octa-4,7-dienoic acid methyl ester 

Relevant academic research and scientific papers

An asymmetric total synthesis of (-)-fumagillol

(-)-Fumagillol (2), a hydrolysis product of fumagillin (1), has been synthesized in a highly stereoselective manner utilizing a glycolate Claisen rearrangement and an intramolecular ester enolate alkylation as key steps starting from carbohydrate-based precursor 5.