192934-27-3Relevant academic research and scientific papers
Electrophilic Addition to Alkoxyethenes. XV. Influence of Structure and Temperature on the Rate of Ethanol Addition
Nedolya, N. A.,Baranskii, V. A.,Trofimov, B. A.
, p. 287 - 290 (2007/10/03)
Rates of acid-catalyzed (in the presence of HCl) addition of ethanol to various alkyl vinyl ethers in the system cyclohexane-ethanol (4:1 by volume) have been measured at 10, 20, 25, 30, and 40 deg C.Linear regression equations have been found that adequately describe the influence of temperature and the substrate structure on the rate constant.The effect of the alkyl substituents includes variable contribution of the steric factor; bulky substituents facilitate the reaction.
