19297-98-4

Upstream product

• 4911-65-3 3-chloropropyl phenyl sulfide 
• 15475-27-1 potassium diphenylphosphine 

Downstream Products

• 96013-32-0 {Rh(bicyclo-hept-1,5-diene)(Ph₂P(CH₂)3SPh)}BF₄ 
• 96029-88-8 {Rh((C₆H₅)2P(CH₂)3SC₆H₅)2}⁽¹⁺⁾*BF₄^(1-)={Rh((C₆H₅)2P(CH₂)3SC₆H₅)2}BF₄ 
• 96029-88-8 Rh((C₆H₅)2P(CH₂)3SC₆H₅)2⁽¹⁺⁾*BF₄^(1-) = Rh((C₆H₅)2P(CH₂)3SC₆H₅)2BF₄ 
• 1259037-30-3 [Rh(CH(SPh)CH2CH2PPh2-κC,κP)(cycloocta-1,5-diene)] 
• 1309230-41-8 [Rh[Ph2P(CH2)3SPh-κP,κS](cycloocta-1,5-diene)][BF4] 
• 1259037-28-9 Rh(CH[SPh]CH2CH2PPh2-κC,κP)(bis(diphenylphosphino)ethane) 
• 1309230-46-3 [Rh[Ph2P(CH2)3SPh-κP,κS](bis(diphenylphosphino)ethane)][BF4] 
• 1388622-43-2 [ruthenium(II)(dichloride)(η6-p-cymene)(PPh2(CH2)3SPh)] 
• 1618084-65-3 IrCl₂(η⁵-C₅Me5){Ph₂PCH₂CH₂CH₂SPh-κP} 
• 1259037-01-8 [RhCl(Ph2PCH2CH2CH2SPh-κP)(dppm)] 
• 1259037-11-0 [Rh(Ph2PCH2CH2CH2SPh-κP,κS)(dppm)][PF6] 
• 1259037-29-0 [Rh(CH(SPh)CH2CH2PPh2-κC,κP)(dppp)] 
• 1259037-15-4 [Rh(Ph2PCH2CH2CH2SPh-κP,κS)(dppp)][PF6] 

Relevant academic research and scientific papers

Catalyst compositions

Catalyst compositions based upon a) a palladium compound, b) an anion of an acid with a pKa of less than 2, and c) a compound of the general formula R1R2M1-R-M2R3, wherein M1 is phosphorus or arsenic, M2 is sulphur or selenium, R1 and R2 are the same or different, optionally polar-substituted, aryl groups, R3 is an optionally polar-substituted hydrocarbyl group and R is a bivalent bridging group containing at least two carbon atoms in the bridge, are useful for the production of polyketone polymers.

Complexes of platinum group metals with the ambidentate ligands Ph2P(CH2)nSPh (n=1, 2 )

The potencially bidentate ligands Ph2P(CH2)nSPh (n=1,2) form complexes of rhodium(I), iridium(I), palladium(II), or platinum(II) in which ligands are coordinated to a metal centre either by the phosphine function alone, or by the phosphine and the thioeth