193006-80-3

Upstream product

• 193006-89-2 ethyl (E)-3-(dimethyl(phenyl)silyl)-2-butenoate 
• 768-33-2 phenyldimethylsilyl chloride 
• 104066-57-1 (E)-3-(dimethyl(phenyl)silyl)but-2-en-1-ol 
• 56583-95-0 1-(dimethyl(phenyl)silyl)ethanone 
• 193006-76-7 [(E)-3-(2,2-Bis-phenylsulfanyl-cyclohexyl)-1-methyl-propenyl]-dimethyl-phenyl-silane 
• 108-94-1 cyclohexanone 

Relevant academic research and scientific papers

Highly stereoselective syntheses of alkenylsilanes and germanes utilizing cyclobutyl ketones

(E)-Alkenylsilanes were synthesized with high stereoselectivity by the diastereoselective addition of the dimethylphenylsilyllithium to the trans-2-phenylthiocyclobutyl ketones and the Lewis acid-promoted promoted stereospecific ring opening reactions of the resulting cyclobutanemethanol derivatives. (E)-1,5-Disubstituted 1,5-dienylsilanes and germanes were also produced stereoselectively by the similar zinc salt-catalyzed ring opening reaction of α-dimethylphenylsilyl- or α-triethylgermyl-1-[2-(trimethylsilylmethyl)cyclobutane]methanol derivatives.