193007-04-4

Basic information

• Product Name: Cyclohexanone, 2-[3-(dimethylphenylsilyl)-2-butenyl]-, (Z)-
• CAS NO: 193007-04-4
• Molecular Formula: C18H26OSi
• Molecular Weight: 286.489
• Mol File: 193007-04-4.mol

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-[3-(dimethylphenylsilyl)-2-butenyl]-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-[3-(dimethylphenylsilyl)-2-butenyl]-, (Z)-(193007-04-4)
• EPA Substance Registry System: Cyclohexanone, 2-[3-(dimethylphenylsilyl)-2-butenyl]-, (Z)-(193007-04-4)

Safety Data

• Hazardous Substances Data: 193007-04-4(Hazardous Substances Data)

Upstream product

• 193006-90-5 ethyl (Z)-3-(dimethyl(phenyl)silyl)-2-butenoate 
• 151710-66-6 (Z)-3-(dimethylphenylsilyl)but-2-en-1-ol 
• 56583-95-0 1-(dimethyl(phenyl)silyl)ethanone 
• 108-94-1 cyclohexanone 
• 768-33-2 phenyldimethylsilyl chloride 

Relevant articles and documents

Highly stereoselective syntheses of alkenylsilanes and germanes utilizing cyclobutyl ketones

(E)-Alkenylsilanes were synthesized with high stereoselectivity by the diastereoselective addition of the dimethylphenylsilyllithium to the trans-2-phenylthiocyclobutyl ketones and the Lewis acid-promoted promoted stereospecific ring opening reactions of the resulting cyclobutanemethanol derivatives. (E)-1,5-Disubstituted 1,5-dienylsilanes and germanes were also produced stereoselectively by the similar zinc salt-catalyzed ring opening reaction of α-dimethylphenylsilyl- or α-triethylgermyl-1-[2-(trimethylsilylmethyl)cyclobutane]methanol derivatives.