19319-00-7Relevant academic research and scientific papers
Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl)hydridoiron complexes as a catalyst precursor
Itazaki, Masumi,Kamitani, Masahiro,Nakazawa, Hiroshi
, p. 7854 - 7856 (2011/08/22)
Catalytic trans-selective hydrogermylation of terminal and internal alkynes was attained by a methyliron complex, CpFe(CO)2(Me), and a bis(germyl)hydridoiron(iv) complex as a catalyst precursor. The structures of (Z)-triphenyl-(2-phenylethenyl)germane and the bis(germyl)hydridoiron(iv) complexes CpFe(CO)(H)(GeR3)2 (R = Et, Ph) were confirmed by single crystal X-ray diffraction studies.
