193292-90-9

Basic information

• Product Name: 1,3-Octanediol, (3S)-
• CAS NO: 193292-90-9
• Molecular Formula: C8H18O2
• Molecular Weight: 146.23
• Mol File: 193292-90-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-Octanediol, (3S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Octanediol, (3S)-(193292-90-9)
• EPA Substance Registry System: 1,3-Octanediol, (3S)-(193292-90-9)

Safety Data

• Hazardous Substances Data: 193292-90-9(Hazardous Substances Data)

Upstream product

• 89461-51-8 [(2S,3S)-3-pentyloxiran-2-yl]methanol 
• 106062-78-6 (2R,3S)-3-pentyloxiranemethanol 

Downstream Products

• 676236-13-8 (4S,5S)-5-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-octyl]-4-[7-(4-methoxy-benzyloxy)-hept-2-ynyl]-cyclopent-2-enone 
• 676236-14-9 dienone compound 
• 676236-03-6 dienone compound 
• 102839-03-2 Δ12-prostaglandin J₂ 
• 202188-43-0 (2R,4S)-2-methyl-4-pentyl-1,3-dioxane 
• 202188-43-0 (2S,4S)-2-methyl-4-pentyl-1,3-dioxane 

Relevant articles and documents

Total synthesis of Δ12-PGJ2, 15-deoxy-Δ12,14-PGJ2, and related compounds

A key cyclopentenone possessing the α-chain was synthesized from TBS ether of 4-cyclopentene-1,3-diol monoacetate, and submitted to aldol reaction at the α′-position with the ω-chain aldehydes followed by dehydration to produce the title compounds. In a similar manner, 5-dehydro compounds (acetylene analogues) were synthesized successfully. In addition, palladium-catalyzed reaction of 4-cyclopentene-1,3-diol monoacetate with methyl malonate, the first step of the synthesis, was improved to afford the product in high yield by using t-BuOK or LDA in place of NaH.