193337-52-9

Upstream product

• 1078-19-9 6-methoxy-3,4-dihydro-1(2H)-naphthalenone 
• 193337-38-1 (E)-5-(2-Formyl-5-methoxy-phenyl)-2-methoxymethoxy-pent-2-enoic acid methyl ester 
• 193337-41-6 (E)-2-Methoxymethoxy-5-{5-methoxy-2-[(E)-2-(methoxy-methyl-carbamoyl)-vinyl]-phenyl}-pent-2-enoic acid methyl ester 
• 193337-43-8 (E)-3-[2-((E)-5-Hydroxy-4-methoxymethoxy-pent-3-enyl)-4-methoxy-phenyl]-propenal 
• 16821-32-2 6-methoxy-1,2,3,4-tetrahydronaphthalen-1-ol 
• 52178-91-3 7-methoxy-1,2-dihydronaphthalene 
• 193337-45-0 (E)-3-[2-((E)-5-Chloro-4-methoxymethoxy-pent-3-enyl)-4-methoxy-phenyl]-propenal 

Downstream Products

• 193337-47-2 tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-methoxymethoxy-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-dimethyl-silane 
• 193337-48-3 (E)-9-{2-[(E)-3-(2,2-Dimethyl-propionyloxy)-propenyl]-5-methoxy-phenyl}-6-methoxymethoxy-3-oxo-non-6-enoic acid methyl ester 
• 193337-53-0 (E)-9-{2-[(E)-3-(tert-Butyl-dimethyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-6-methoxymethoxy-3-oxo-non-6-enoic acid methyl ester 
• 193337-54-1 (E)-9-[2-((E)-3-Hydroxy-propenyl)-5-methoxy-phenyl]-6-methoxymethoxy-3-oxo-non-6-enoic acid methyl ester 

Relevant academic research and scientific papers

Synthesis of a 14β-Hydroxysteroid Using the Transannular Diels-Alder Strategy

Macrocyclic TCC triene 1, generated by an intramolecular alkylation of a β-ketoester on a π-allylpalladium complex followed by dehydrogenation, underwent a highly stereoselective transannular Diels-Alder reaction affording the tetracyclic compound 2 in an excellent yield.