193471-29-3

Upstream product

• 4455-77-0 (methoxymethyl)diphenylphosphine oxide 
• 157519-07-8 (4aS,6S,8aS)-6-(tert-Butyl-diphenyl-silanyloxy)-2,5,5,8a-tetramethyl-4a,5,6,7,8,8a-hexahydro-4H-naphthalen-1-one 
• 157519-06-7 (1R,4aS,6S,8aS)-6-(tert-Butyl-diphenyl-silanyloxy)-2,5,5,8a-tetramethyl-1,4,4a,5,6,7,8,8a-octahydro-naphthalen-1-ol 

Downstream Products

• 193471-32-8 (3S,4aR,8aS)-3-(tert-Butyl-diphenyl-silanyloxy)-8-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,6-bis-methoxymethoxy-benzyl]-4,4,7,8a-tetramethyl-1,2,3,4,4a,5,6,8a-octahydro-naphthalene 
• 193471-35-1 C₅₆H₇₀O₄Si₂ 
• 193471-34-0 C₅₄H₆₇BrO₄Si₂ 
• 193471-37-3 C₅₄H₆₇BrO₄Si₂ 
• 193471-38-4 C₅₆H₇₀O₄Si₂ 
• 193471-33-9 C₅₄H₆₈O₄Si₂ 
• 193471-31-7 tert-Butyl-[(2S,4aS,8aR)-5-(4-dimethoxymethyl-2,6-bis-methoxymethoxy-benzyl)-1,1,4a,6-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-yloxy]-diphenyl-silane 
• 193471-30-6 ((2S,4aS,8aR)-5-Bromomethyl-1,1,4a,6-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-yloxy)-tert-butyl-diphenyl-silane 

Relevant academic research and scientific papers

Synthesis and structure revision of the myo-inositol monophosphatase inhibitor l-671,776

Concomitant deprotection/spiro-heteroannulation of 6 utilizing (EtO)3SiI was exploited for the asymmetric total synthesis of the title tetracyclic terpenoid whose structure was revised to 13.