19349-52-1

Upstream product

• 110-86-1 pyridine 
• 173605-92-0 fac-molybdenum(CO)3(bis-(1,2-diphenylphosphino)ethane)(η-C60) 
• 84411-54-1 mer-Tricarbonyl[bis(diphenylphosphino)ethan](dimethylmaleat)molybdaen 
• 66701-87-9 tricarbonyltris(pyridine)molybdenum 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Downstream Products

• 115889-91-3 fac-(4-methyl-2,6,7-trioxa-1-phodphabicyclo{2.2.2}octane)-1,2-bis(diphenylphosphino)ethaneMo(CO)3 
• 115940-58-4 fac-tetracarbonyl(triethyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum 
• 67265-36-5 fac-[1,2-bis(diphenylphosphino)ethane](triisopropylphosphite)tricarbonylmolybdenum⁽⁰⁾ 
• 115889-92-4 fac-{(P(o-tol)Ph₂)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3 
• 115940-59-5 fac-{(PPh₃)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3 
• 1032101-59-9 fac-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum 
• 19349-54-3 fac-{(SbPh₃)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3 

Relevant academic research and scientific papers

Metal-template-controlled stabilization of β-functionalized isocyanides

Reaction of 2-azidoethyl isocyanide 1, 2-azidophenyl isocyanide 2, or 2-nitrophenyl isocyanide 3 with complexes [Mo(CO)3(dppe)(py)] [4] or [W(CO)3(dppe)(Ni-≡CCH3)] [5] yields the isocyanide complexes [Mo(CO)3(dp

The chemical reactivity of fullerene C60 towards fac-Mo(Co)3 (MeCN)(dppe) and Mo(Co)4(dppe). Synthesis, characterization and reactions of the novel fullerene molybdenum derivative fac-Mo(Co)3(dppe)(n2

The acetonitrile ligand of fac-Mo(CO)3(MeCN)(dppe)[dppe = bis-(1,2-diphenylphosphino)ethane] can be easily replaced by fullerene C60 in chlorobenzene at about 8O°C to give exclusively fac-Mo(CO)3(dppe)(n2- Csub

Carbonyl Monoolefin Derivatives of the Group VI Transition Metals. III. Preparation and Reactivity of Tricarbonyl Chelate Phosphane Olefin Derivatives

Monoolefin complexes M(CO)3(R2PC2H4PR2)(ol) (M = Cr, Mo, W; R = CH3, C6H5; ol = maleic anhydride, dimethyl fumarate, dimethyl maleate, methyl acrylate, ethylene, styrene, norbornene) are obtained photochemically from the tetracarbonyl chelate phosphane derivatives.Facial complexes are formed primarily, some of which rearrange intramolecularly to the meridional isomers.The substitution of the olefin proceeds via a dissociative mechanism, the meridional isomers rearrange back to the facial ones prior to the rupture of the metal-olefin bond.