19349-52-1

Basic information

• Product Name: [Mo(CO)₃(dppe)(py)]
• CAS NO: 19349-52-1
• Molecular Weight: 657.497
• Mol File: 19349-52-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [Mo(CO)₃(dppe)(py)](CAS DataBase Reference)
• NIST Chemistry Reference: [Mo(CO)₃(dppe)(py)](19349-52-1)
• EPA Substance Registry System: [Mo(CO)₃(dppe)(py)](19349-52-1)

Safety Data

• Hazardous Substances Data: 19349-52-1(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 173605-92-0 fac-molybdenum(CO)3(bis-(1,2-diphenylphosphino)ethane)(η-C60) 
• 66701-87-9 tricarbonyltris(pyridine)molybdenum 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 
• 84411-54-1 mer-Tricarbonyl[bis(diphenylphosphino)ethan](dimethylmaleat)molybdaen 

Downstream Products

• 67265-36-5 fac-[1,2-bis(diphenylphosphino)ethane](triisopropylphosphite)tricarbonylmolybdenum⁽⁰⁾ 
• 19349-54-3 fac-{(SbPh₃)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3 
• 115940-59-5 fac-{(PPh₃)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3 
• 1032101-59-9 fac-tetracarbonyl(triphenyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum 
• 115889-92-4 fac-{(P(o-tol)Ph₂)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3 
• 115940-58-4 fac-tetracarbonyl(triethyl phosphite)(1,2-bis(diphenylphosphino)ethane)molybdenum 
• 115889-91-3 fac-(4-methyl-2,6,7-trioxa-1-phodphabicyclo{2.2.2}octane)-1,2-bis(diphenylphosphino)ethaneMo(CO)3 

Relevant articles and documents

Metal-template-controlled stabilization of β-functionalized isocyanides

Reaction of 2-azidoethyl isocyanide 1, 2-azidophenyl isocyanide 2, or 2-nitrophenyl isocyanide 3 with complexes [Mo(CO)3(dppe)(py)] [4] or [W(CO)3(dppe)(Ni-≡CCH3)] [5] yields the isocyanide complexes [Mo(CO)3(dp

Carbonyl Monoolefin Derivatives of the Group VI Transition Metals. III. Preparation and Reactivity of Tricarbonyl Chelate Phosphane Olefin Derivatives

Monoolefin complexes M(CO)3(R2PC2H4PR2)(ol) (M = Cr, Mo, W; R = CH3, C6H5; ol = maleic anhydride, dimethyl fumarate, dimethyl maleate, methyl acrylate, ethylene, styrene, norbornene) are obtained photochemically from the tetracarbonyl chelate phosphane derivatives.Facial complexes are formed primarily, some of which rearrange intramolecularly to the meridional isomers.The substitution of the olefin proceeds via a dissociative mechanism, the meridional isomers rearrange back to the facial ones prior to the rupture of the metal-olefin bond.