193681-06-0

Basic information

• Product Name: Pt(P(C6H11)3)2(η(2)-C60)
• CAS NO: 193681-06-0
• Molecular Weight: 1476.61
• Mol File: 193681-06-0.mol

Chemical Properties

• CAS DataBase Reference: Pt(P(C6H11)3)2(η(2)-C60)(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(P(C6H11)3)2(η(2)-C60)(193681-06-0)
• EPA Substance Registry System: Pt(P(C6H11)3)2(η(2)-C60)(193681-06-0)

Safety Data

• Hazardous Substances Data: 193681-06-0(Hazardous Substances Data)

Upstream product

• 824391-83-5 trans-dihydridobis(tricyclohexylphosphine)platinum 
• 99685-96-8 fullerene-C₆₀ 

Relevant articles and documents

Reaction of trans-[Pt(H)2(PCy3)2] with C60 Reductive elimination of H2 and formation of [Pt(PCy3)2(η2-C60)]

Reaction of trans-[Pt(H)2(PCy3)2], 1, with [60]fullerene at room temperature affords [Pt(PCy3)2(η2-C60)], 2, in nearly quantitative yield. The most probable reaction pattern is the insertion of a fullerene 6,6 junction onto a Pt-H bond yielding an η1 alkyl derivative which, after hydrogen extrusion, gives 2. On the other hand, addition of 1 to different electron-deficient olefins, such as dimethyl maleate and fumarate, furnishes mixtures of both η1 metal-alkyl and η2 metal-olefin derivatives. If tetrachloroethylene is used as 27π component, trans-[PtCl(H)(PCy3)2] forms exclusively.