193944-67-1Relevant articles and documents
Synthesis of 4'-azido-2,2':6',2''-terpyridines and their iron(II) and ruthenium(II) complexes
Fallahpour, Reza-Ali,Neuburger, Markus,Zehnder, Magareta
, p. 1051 - 1055 (1999)
Three different 4'-azido-2,2':6',2''-terpyridines have been synthesised. The structure of 4'-azido-2,2':6',2''-terpyridine was determined by X-ray crystal structure analysis. The iron(II) complex of this ligand has been prepared, while the azide group was reduced to amine in the ruthenium(II) complex under the reaction conditions.
The design and synthesis of bis-[4'-azido-2,2':6',2-terpyridine platinum(II)] complexes with rigid and extended linkers for studying the topology of DNA by photoaffinity labeling
Lowe, Gordon,Droz, Anne-Sophie,Park, Jenny J.,Weaver, George W.
, p. 477 - 486 (2007/10/03)
A family of bis-[4'-Azido-2,2':6',2''-terpyridine platinum(II)] complexes with linear linkers of varying length have been synthesized. They have been designed to bis-intercalate into two DNA duplexes in close proximity, the azido groups allowing the sites of intercalation to be photoaffinity labeled. The linker to Pt(II) bonds are susceptible to cleavage by thiols and cyanide ion, which is a requirement for the intended method of analysis by 2D gel electrophoresis. (C) 1999 Academic Press.