19397-91-2

Upstream product

• 75-18-3 dimethylsulfide 
• 39536-32-8 sodium benzamidate 
• 55-21-0 benzamide 
• 67-68-5 dimethyl sulfoxide 
• 61945-93-5 N,N'-dibenzoylselenium diimide 
• 25408-75-7 N,N'-dibenzoylsulfur diimide 
• 57738-66-6 S,S-dimethyl-S-(trifluoroacetoxy)sulfonium trifluoroacetate 
• 19226-36-9 3-phenyl-5H-1,4,2-dioxazol-5-one 
• 495-18-1 Benzohydroxamic acid 

Downstream Products

• 31280-33-8 N-(benzoyl)-S,S-dimethylsulfoximine 
• 75-18-3 dimethylsulfide 
• 55-21-0 benzamide 
• 30216-02-5 2,5,5-triphenyl-2-oxazolin-4-one 
• 59305-76-9 dichloro(dimethylphenylphosphine)(S,S-dimethyl-N-benzoylsulfilimine)platinum(II) 
• 59305-77-0 dichloro(triphenylphosphine)(S,S-dimethyl-N-benzoylsulfilimine)platinum(II) 
• 59306-17-1 dichloro(triphenylphosphine)(S,S-dimethyl-N-benzoylsulfilimine)palladium(II) 
• 1337936-32-9 N-(2,5-diphenyloxazol-4-yl)-N-phenylmethanesulfonamide 

Relevant academic research and scientific papers

Gold(III)-Catalyzed Formal [3 + 2] Annulations of N-Acyl Sulfilimines with Ynamides for the Synthesis of 4-Aminooxazoles

A gold-catalyzed formal 1,3-dipolar [3 + 2] annulation using readily accessible N-acyl sulfilimines and ynamides is reported. This reaction includes the cleavage of a N-S bond and subsequent C-O bond formation. In total, 30 oxazole derivatives bearing div

Light-induced ruthenium-catalyzed nitrene transfer reactions: A photochemical approach towards N-Acyl sulfimides and sulfoximines

1,4,2-Dioxazol-5-ones are five-membered heterocycles known to decarboxylate under thermal or photochemical conditions, thus yielding N-acyl nitrenes. Described herein is a light-induced ruthenium-catalyzed N-acyl nitrene transfer to sulfides and sulfoxides by decarboxylation of 1,4,2-dioxazol-5-ones at room temperature, thus providing direct access to N-acyl sulfimides and sulfoximines under mild reaction conditions. In addition, a one-pot sulfur imidation/oxidation sequence catalyzed by a single ruthenium complex is reported. Double duty: A one-pot sulfur imidation/oxidation sequence using a single ruthenium complex for both steps was developed (see scheme). Photochemical decarboxylations of 1,4,2-dioxazol-5-ones provide N-acyl nitrenes, which imidate sulfides at ambient temperature. The subsequent oxidation then occurs under mild phase-transfer catalysis conditions. In this manner, N-acyl sulfimides and sulfoximines can be obtained in high yields starting from sulfides.

N-(4-bromobenzoyl)-S,S-dimethyliminosulfurane, a potent dermal penetration enhancer

N-Aroyl-, N-Arylsulfonyl-, and N-Aryl-S,S-dimethyliminosulfuranes have been synthesized and evaluated as potential dermal penetration enhancers. The title compound and Azone exhibit similar activities for permeation of hydrocortisone through hairless mouse skin.

N,N'-DIACYLSELENIUM AND N,N'-DIACYLSULFUR DIIMIDES

In the reaction of N,N'-diphenylsulfonylselenium diimide (C6H5SO2N=)2Se with aldehydes, dimethyl sulfoxide, diphenyl selenone, diphenyl selenoxide, triphenylphosphine oxide, etc. the oxygen atom in the E=O group is substituted by a phenylsulfonylimino group.In the reaction of triphenylphosphine with N,N'-diphenylsulfonylselenium diimide N,N'-diphenylsulfonyl-N-triphenylphosphoniohydrazinate is formed.In the reaction of triphenylphosphine with N,N-diacylselenium or N,N'-diacylsulfur sulfimides (CH3CON=)2Se, (C6H5CON=)2Se or (C6H5CON=)2S triphenylphosphine oxide, the corresponding nitrile, and selenium or sulfur are obtained.