194094-95-6

Upstream product

• 501-53-1 benzyl chloroformate 
• 615-43-0 2-iodophenylamine 
• 106-95-6 allyl bromide 
• 212063-19-9 N-(benzyloxycarbonyl)-2-iodoaniline 

Downstream Products

• 275356-29-1 benzyl 3-(2-methoxy-2-oxoethyl)-4-oxo-3,4-dihydro-1(2H)-quinolinecarboxylate 
• 246257-97-6 N-allyl-N-(benzyloxycarbonyl)aniline 
• 275356-38-2 benzyl (3aS,9bS)-1-[(1R)-2-hydroxy-1-phenylethyl]-2-oxo-1,2,3,3a,4,9b-hexahydro-5H-pyrrolo[3,2-c]quinoline-5-carboxylate 
• 275356-30-4 benzyl (2aS,8bR,11R)-1-oxo-11-phenyl-1,2,2a,3,10,11-hexahydro-4H-[1,3]oxazolo[3',2':1,2]pyrrolo[3,2-c]quinoline-4-carboxylate 
• 275356-31-5 (3aS,9bS)-1-[(1R)-2-hydroxy-1-phenylethyl]-1,3,3a,4,5,9b-hexahydro-2H-pyrrolo[3,2-c]quinolin-2-one 
• 275356-36-0 2-{1-[(benzyloxy)carbonyl]-4-oxo-1,2,3,4-tetrahydro-3-quinolinyl}acetic acid 
• 275356-37-1 (3aS,9bS)-1-(1-phenylvinyl)-1,3,3a,4,5,9b-hexahydro-2H-pyrrolo[3,2-c]quinolin-2-one 

Relevant academic research and scientific papers

Diastereoselective intramolecular SmI2-H2O-amine mediated couplings

The effectiveness of SmI2-H2O-amine mixture for intramolecular couplings was discussed. Diastereoselectivities in the coupling of O-cyclohexanyliodophenol derivatives were provided into heterocycles. The amount of coupled product improved significantly as SmI2, the substrate and amine were premixed followed by a gradual addition of water.