194097-16-0

Basic information

• Product Name: Phosphine, bis[(1,1-dimethylethyl)fluoro[2,4,6-tris(1-methylethyl)phenyl]silyl]-
• CAS NO: 194097-16-0
• Molecular Formula: C38H65F2PSi2
• Mol File: 194097-16-0.mol

Chemical Properties

• CAS DataBase Reference: Phosphine, bis[(1,1-dimethylethyl)fluoro[2,4,6-tris(1-methylethyl)phenyl]silyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine, bis[(1,1-dimethylethyl)fluoro[2,4,6-tris(1-methylethyl)phenyl]silyl]-(194097-16-0)
• EPA Substance Registry System: Phosphine, bis[(1,1-dimethylethyl)fluoro[2,4,6-tris(1-methylethyl)phenyl]silyl]-(194097-16-0)

Safety Data

• Hazardous Substances Data: 194097-16-0(Hazardous Substances Data)

Downstream Products

• 194097-12-6 C₃₈H₆₄FPSi₂ 

Relevant articles and documents

R2Si=P-SiR2F: 1,3-Sigmatropic migration of fluorine in a 2-phospha-1,3-disilaallyl derivative capable of conjugation and its conversion to phosphadisilacyclopropanes

More electronically diverse than the behavior of allyl is that of the 2-phospha-1,2-disilaallyl fragment. This was confirmed by the [1,3]-sigmatropic shift of fluorine in the title compound 1, which occurred rapidly at temperatures above 40°C. Ab initio c