194220-83-2Relevant academic research and scientific papers
Enantioselective ring opening of tropinone. a new entry into tropane alkaloids
Majewski, Marek,Lazny, Ryszard,Ulaczyk, Agnieszka
, p. 754 - 761 (2007/10/03)
The lithium enolate of tropinone reacts with alkyl chloroformates to give 6-N-carboalkoxy-N-methyl-2-cycloheptenones (4). These compounds can be produced enantioselectively, in up to 95% ee, if chiral lithium amides (derived from optically pure amines 5-7
