194297-36-4Relevant academic research and scientific papers
Synthesis of hydroxy(or hydroperoxy)-substituted 1,2,4- trioxacycloalkanes by the ozonolysis of unsaturated hydroperoxy acetals
Ushigoe,Torao,Masuyama,Nojima
, p. 4949 - 4954 (1997)
Ozonolyses of unsaturated hydroperoxy acetals 4a-k gave in each case the mixtures of products containing the corresponding trioxanes 8a-f and 12e,f, trioxepanes 12g-i, trioxocane 12j, and trioxonane 12k. By choosing the proper conditions of the ozonolysis, the desired cyclic peroxide was selectively obtained in moderate to good yield. Alternatively, acid-catalyzed cyclization of the methanol-derived ozonolysis products 13h and 13j provided the corresponding trioxepane 12h and trioxocane 12j, respectively.
