19437-28-6

Basic information

• Product Name: 1-isopropyl-4-tert-butyl cyclohexanol(eq)
• Synonyms: 1-isopropyl-4-tert-butyl cyclohexanol(eq)
• CAS NO: 19437-28-6
• Molecular Weight: 198.349
• Mol File: 19437-28-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-isopropyl-4-tert-butyl cyclohexanol(eq)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-isopropyl-4-tert-butyl cyclohexanol(eq)(19437-28-6)
• EPA Substance Registry System: 1-isopropyl-4-tert-butyl cyclohexanol(eq)(19437-28-6)

Safety Data

• Hazardous Substances Data: 19437-28-6(Hazardous Substances Data)

Upstream product

• 98-53-3 4-tercbutyl-cyclohexanone 
• 920-39-8 isopropylmagnesium bromide 
• 75-30-9 2-iodo-propane 

Downstream Products

• 14033-75-1 1-(tert-butyl)-4-(propan-2-ylidene)cyclohexane 
• 63089-67-8 4-tert-butyl-1-isopropylcyclohexene 

Relevant articles and documents

STRUCTURAL INFORMATION FROM OH STRETCHING FREQUENCIES-X. OH-ROTAMER DISTRIBUTION IN AXIAL TERTIARY CYCLOHEXANOLS

The presence of preferential OH-rotamers in axial tertiary cyclohexanols dissolved in CCl4 has been studied by means of the i.r. absorption of the OH-stretching vibration.Favoured OH-rotamers exist, the origin being interactions betwwen the OH-proton and

The samarium grignard reaction. In situ formation and reactions of primary and secondary alkylsamarium(III) reagents

This work shows that primary and secondary radicals are rapidly reduced in THF/HMPA to form primary- and secondary-alkylsamarium reagents. The primary- and secondary-radicals can be formed either by direct SmI2 reduction of primary- and secondary-halides or by a previous rapid radical cyclization. The samarium reagents have moderate stability in solution, and they react with a variety of typical electrophiles, including aldehydes and ketones. The work further shows that organosamarium intermediates can be involved in the traditional samarium Barbier reaction of aldehydes and ketones conducted in THF/HMPA. A new procedure called the "samarium Grignard" method is introduced, and it is suggested that this new procedure will have considerably more scope and generality than the samarium Barbier reaction.