19446-95-8Relevant academic research and scientific papers
ALIPHATISCHE DIAZOVERBINDUNGEN. XI. SYNTHESE UND CYCLISIERUNG SELEN- BZW. TELLUR-HALTIGER ω-DIAZO-ACETOPHENONE ZU SELENO-BZW. TELLURO-3-CUMARANON
Lohner, W.,Praefcke, K
, p. 173 - 178 (1980)
The syntheses and chemical behaviour of ortho-butylseleno-and ortho-butyl-telluro-substituted ω-diazoacetophenones are described for the first time.Seleno- and telluro-3-coumaranone are obtained by novel routes involving cyclization of these diazoketones.
LITHIUM DISELENIDE IN APROTIC MEDIUM - A CONVENIENT REAGENT FOR SYNTHESIS OF ORGANIC DISELENIDES
Syper, Ludwik,Mlochowski, Jacek
, p. 6119 - 6130 (2007/10/02)
The reduction of selenium with lithium in THF in the presence of diphenylacetylene as a catalyst afforded lithium diselenide, which reacted with electrophiles giving alkyl or aryl diselenides 1 - 3 and selenides 4, as by-products.The useful method for preparation of diselenides based on this reaction was elaborated.
