194482-45-6Relevant academic research and scientific papers
Highly selective hydrosilylation of olefins and acetylenes by platinum(0) complexes bearing bulky N-heterocyclic carbene ligands
Zak,Bo?t,Kubicki,Pietraszuk
supporting information, p. 1903 - 1910 (2018/02/17)
Platinum complexes bearing bulky N-heterocyclic carbene (NHC) ligands, i.e., [Pt(IPr?)(dvtms)] (where, IPr? = 1,3-bis{2,6-bis(diphenylmethyl)-4-methylphenyl}imidazol-2-ylidene) and [Pt(IPr?OMe)(dvtms)] (where, IPr?OMe = 1,3-bis{2,6-bis(diphenylmethyl)-4-m
Hydrosilylation of functionalised olefins catalysed by rhodium siloxide complexes in ionic liquids
MacIejewski, Hieronim,Szubert, Karol,Marciniec, Bogdan,Pernak, Juliusz
experimental part, p. 1045 - 1051 (2010/04/23)
The use of ionic liquids for the immobilization of rhodium siloxide complexes has permitted development of highly effective catalysts for the hydrosilylation processes. Herein, we report the synthesis of organosilicon compounds in a biphasic reaction setup, allowing separation of the product, recovery and reuse of the catalyst, which is fundamental from the point of view of "green chemistry".
