194614-25-0Relevant academic research and scientific papers
Reactions of [60]fullerene with halides and amino acids to synthesize fulleropyrrolidines
Jin, Bo,Shen, Juan,Peng, Rufang,Chen, Congdi,Chu, Shijin
, p. 6252 - 6262 (2014)
The reactions of [60]fullerene with benzyl chlorides and amino acids in chlorobenzene (PhCl) were investigated. Fulleropyrrolidines bearing ArCH moieties originating from the corresponding benzyl chlorides through C-Cl bond cleavage were obtained from these reactions. Use of PhCl/DMSO instead of PhCl as the solvent significantly improved the reaction efficiency. A detailed investigation of these reactions resulted in the discovery of other halides - such as allyl chloride, methallyl chloride, cinnamyl chloride, propargyl bromide, ethyl bromoacetate, bromoacetonitrile, bromomethane, bromopropane and bromobutane - that could also react with [60]fullerene and amino acids to produce fulleropyrrolidines. This reaction could be an alternative to the Prato reaction for synthesizing fulleropyrrolidines when aldehydes are expensive or unavailable from commercial sources. A plausible reaction mechanism for product formation involving C-X bond cleavage in the halide to form the aldehyde is proposed.
Synthesis and oxidation of vinyl derivatives of N-methyl[60]fullereno[c] pyrrolidine
Abramova,Ginzburg,Sokolov
scheme or table, p. 1964 - 1966 (2011/07/08)
Novel organometallic derivatives of N-methyl[60]fullereno[c]pyrrolidine bearing the vinyl fragment at the position 2 of the pyrrolidine ring were synthesized. Their oxidation with 3-chloroperoxybenzoic acid to give N-oxides and epoxides was studied in det
