194668-79-6

Upstream product

• 96-35-5 glycolic acid methyl ester 
• 166828-15-5 4,5,6,8-tetra-O-benzyl-1,2-dideoxy-α-D-gluco-oct-1-eno-3-ulopyranose 

Downstream Products

• 194668-84-3 (R)-2-(Diphenoxy-phosphoryloxy)-4-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-butyric acid methyl ester 
• 194668-86-5 (S)-2-Azido-4-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-butyric acid methyl ester 
• 194668-81-0 (R)-2-Hydroxy-4-[(3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-(2Z)-ylidene]-butyric acid methyl ester 
• 194668-83-2 (R)-2-Hydroxy-4-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-butyric acid methyl ester 

Relevant academic research and scientific papers

Stereoselective synthesis of the C-analogue of β-D-glucopyranosyl serine

The [2,3]-Wittig sigmatropic rearrangement of an appropriate glucose derivative followed by further chemical modification afforded stereoselectively the C-analogue of β-D-glucopyranosyl serine.