19470-77-0

Upstream product

• 2216-51-5 (-)-menthol 
• 75-78-5 dimethylsilicon dichloride 

Downstream Products

• 125638-08-6 (2,2-Dimethyl-1-methylene-propoxy)-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-dimethyl-silane 
• 125556-74-3 (Cyclohex-1-enyloxy)-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-dimethyl-silane 
• 18782-87-1 ((1S,2R,5S)-2-Isopropyl-5-methyl-cyclohexyloxy)-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-dimethyl-silane 
• 125556-76-5 ((E)-1-Ethyl-propenyloxy)-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-dimethyl-silane 
• 123464-08-4 allyl<(-)-menthoxy>dimethylsilane 
• 125556-75-4 ((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxy)-dimethyl-(1-phenyl-vinyloxy)-silane 

Relevant academic research and scientific papers

CHIRAL ORGANOSILICON COMPOUNDS. PART 1. SYNTHESIS OF CHIRAL SILYL ENOL ETHERS

A convenient synthesis of menthol- and borneol-derived chiral silyl enol ethers is described.

Lewis Acid Promoted Condensation of Allylalkoxysilanes with Carbonyl Co+pounds. Synthesis of Tetrahydropyrans

Allylalkoxysilanes 1 condense with aldehydes under Lewis acid conditions to give cis-2,4,6-trisubstituted tetrahydropyrans 3 or the homoallylic alcohols 2.Factors affecting the reaction have been examined.The enantioselective synthesis of 2 using optically active 1 has also been studied.The reaction is applied to the enantioselective synthesis of (6'-methyl-2'-tetrahydropyranyl)acetic acid (11), a natural compound that has been isolated from the glandular secretion of the civet cat.