194807-96-0

Upstream product

• 158852-31-4 3,4,6-tri-O-benzyl-1,2-O-(exo-ethoxyethylidene)-α-D-glucopyranose 

Downstream Products

• 96323-30-7 methyl 4-O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-2,3,6-tri-O-benzyl-α-D-galactopyranoside 
• 98906-48-0 methyl 2-O-acetyl-3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-1→4-(2,3,6-tri-O-benzyl)-β-D-glucopyranoside 
• 125085-08-7 methyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 451463-10-8 (Z)-2-O-prop-1'-enyl-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride 
• 358351-83-4 2-O-(2-iodo-1-(methyl-2,3,4-tri-O-benzyl-α-D-mannopyranosid-6-O-yl)-propyl)-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride 
• 358351-85-6 2-O-(2-iodo-1-(methyl-2,3,6-tri-O-benzyl-α-D-glucopyranosid-4-O-yl)-propyl)-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride 
• 358351-84-5 2-O-(2-iodo-1-(methyl-2-O-benzyl-4-6-O-benzylidene-α-D-mannopyranosid-3-O-yl)-propyl)-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride 
• 358351-82-3 2-O-(1-(1,2:3,4-di-O-isopropylidene-α-D-galactopyranos-6-O-yl)-2-iodopropyl)-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride 
• 358351-81-2 2-O-(1-cyclohexyloxy-2-iodopropyl)-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride 
• 358351-69-6 2-O-(2-iodo-1-methoxypropyl)-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride 
• 358351-60-7 2-O-allyl-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride 
• 40246-33-1 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1→6)-1:2,3:4-di-O-isopropylidene-α-D-galactopyranoside 
• 74372-92-2 3,4,6-Tri-O-benzyl-β-D-glucopyranosyl fluoride 

Relevant academic research and scientific papers

Stereospecific synthesis of 1,2-cis glycosides by allyl-mediated intramolecular aglycon delivery. 2.The use of glycosyl fluorides.

[reaction: see text] Stereospecific 1,2-cis glycosylation of 2-O-allyl-protected glucosyl and mannosyl fluorides via a sequence of allyl isomerization, N-iodosuccinimide-mediated tethering, and intramolecular aglycon delivery (IAD) is reported. The use of

Allyl protecting group mediated intramolecular aglycon delivery (IAD) of glycosyl fluorides

Stereospecific 1,2-cis-glycosylation of 2-O-allyl protected glucosyl and mannosyl fluorides can be achieved via a sequence of allyl isomerization, N-iodosuccinimide mediated tethering, and intramolecular aglycon delivery (IAD). Fluoride is advantageous as