19488-10-9Relevant academic research and scientific papers
Nucleophilic Reactivities of Thiophenolates
Jüstel, Patrick M.,Pignot, Cedric D.,Ofial, Armin R.
, p. 5965 - 5972 (2021)
The nucleophilic reactivities of substituted thiophenolates were determined by following the kinetics of their reactions with a series of quinone methides (reference electrophiles) in DMSO at 20 °C. The experimentally determined second-order rate constants were analyzed according to the Mayr-Patz equation log k = sN(N + E) to derive the nucleophile-specific reactivity parameters N and sN for ten thiophenolate ions.
