19490-62-1

Basic information

• Product Name: 3-β-benzyl-5-α-cholestane-3-α-ol
• CAS NO: 19490-62-1
• Molecular Weight: 478.802
• Mol File: 19490-62-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-β-benzyl-5-α-cholestane-3-α-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-β-benzyl-5-α-cholestane-3-α-ol(19490-62-1)
• EPA Substance Registry System: 3-β-benzyl-5-α-cholestane-3-α-ol(19490-62-1)

Safety Data

• Hazardous Substances Data: 19490-62-1(Hazardous Substances Data)

Upstream product

• 566-88-1 cholestan-3-one 
• 53178-41-9 2-lithio-2-phenyl-1,3-dithiane 

Relevant articles and documents

Stereochemistry of Dithianyllithium Addition to Cyclohexanone

The reaction of 2-phenyl-1,3-dithianyllithium (1-Li) with 4-tert-butylcyclohexanone in cyclohexane and tetrahydrofuran may proceed either with kinetic or thermodynamic control.In the latter case carbinol formation involves exclusively equatorial attack.In contrast, only kinetic control is seen in the reaction of the same ketone with 1,3-dithianyllithium (2-Li) or its mono-S-oxide (3-Li).No addition but only enolate formation occurs in solvent hexamethylphosphoric triamide; with 1--4-tert-butylcyclohexanol reversal of the addition reaction is seen in this solvent.