195048-08-9Relevant academic research and scientific papers
Polyene cyclization promoted by the cross conjugated α-carbalkoxy enone system. An efficient approach to highly functionalized decalins
Liu, Hsing-Jang,Sun, Daqing,Shia, Kak-Shan
, p. 453 - 462 (2007/10/03)
The cross conjugated α-carbalkoxy enone system was found to be an excellent promoter for polyene cyclization. Under mild conditions, the reaction occurred readily with a high degree of regio- and stereoselectivity. Based on this facile process, an efficie
Polyene cyclization promoted by the cross conjugated α-carbalkoxy enone system. Application to the total synthesis of (±)-dehydrochamaecynenol
Liu, Hsing-Jang,Sun, Daqing
, p. 6159 - 6162 (2007/10/03)
The title cyclization process has been effectively applied to the first total synthesis of dehydrochamaecynenol in racemic form.
